Reaction Mechanism and Kinetics of Criegee Intermediate Formation in the Ozonolysis of a Marine Chlorinated Monoterpene: A Three-Channel Master-Equation Analysis
Atmospheric ozonolysis of halogenated monoterpenes from marine red macroalgae proceeds through pre-reactive complexes, primary ozonides, Criegee intermediates, and carbonyl products. Structure–activity relationship (SAR) schemes, such as that of Khan et al. (2022) for nineteen Plocamium-derived monoterpenes, return onl...