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Author

A. Dobrynin

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Sep 2026

Toeplitz matrix formulation of polymer physics: From single chain statistics to liquid-crystalline order.

We develop a Toeplitz matrix formulation of polymer statistics that provides a unified, analytically tractable description of flexible and semiflexible chains. Bond-vector correlations are encoded in a Toeplitz matrix, with a single parameter controlling the decay of orientational memory along the backbone. The bead-sp...

A. Dobrynin · 0 citations
Sep 2026

Melts of Brush Copolymers: From Microphase Separation to Liquid-Crystalline Order

We use coarse-grained molecular dynamics simulations to investigate structural organization in melts of brush copolymers as a function of side-chain grafting density, backbone-side-chain miscibility, and backbone rigidity. At low grafting densities, decreasing miscibility drives microphase separation of backbones and...

Zi-Lu Wang, E. Samulski, S. S. Sheiko et al. · 0 citations

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