Ag14 Nanocluster Featuring an Unconventional Non-FCC Metal Skeleton and Its Sensitivity to Oxygen.
Despite the significant advancements in noble metal-based nanocluster research, challenges remain in making specific metal kernel geometries, especially protected by bulky ligand shells. Here, we synthesized and structurally characterized a neutral silver cluster, [Ag14(TRZ)12(TPP)3], where TRZ and TPP refer to 6-(dibu...