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Author

Aleksi Vähäkangas

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Review Open access Aug 2026

From Cages to Sheets: Computational Elucidation of Methylaluminoxane Structure and Reactivity

Methylaluminoxane (MAO) is the most widely used cocatalyst in single‐site olefin polymerization, yet its molecular structures have decisively resisted characterization. Computational chemistry has played an indispensable role throughout the characterization efforts, from the earliest cage‐based structural proposals ins...

Mikko Linnolahti, Perttu Hanhisalo, Aleksi Vähäkangas · 1 citation
Open access Jul 2026

Density functional benchmarks for methylaluminoxane: successes, biases, and transferability limits.

Methylaluminoxane (MAO) is the most widely used cocatalyst for olefin polymerization, yet its molecular structure remains incompletely understood. Computational methods are essential for elucidating the structure and reactivity of MAO, but their accuracy has been difficult to assess. Benchmarking based on trimethylalum...

Aleksi Vähäkangas, Perttu Hanhisalo, Munmun Bharti et al. · 0 citations

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