Nickel-Catalyzed Thiolative Cyclization of Cyclic Enynones under Visible-Light Irradiation: An Easy Access to 9‑Sulfenyl-2,3-dihydrophenanthren-4(1H)‑ones.
An efficient nickel-catalyzed thiolative addition-cyclization of conjugated cyclic enynones for the synthesis of 9-sulfenyl-2,3-dihydrophenanthren-4-(1H)-ones is described. The reaction proceeds through a nickel-catalyzed hydrothiolation of cyclic enynones, followed by visible-light-induced intramolecular cyclization....