Bao-Yu Huang

Structural Fluxionality of Surface Motifs in Positional Isomeric Au14Cd2 Clusters Enables Switchable O–O Bond Activation Pathways

The construction of positional isomers enables tunable control over the physicochemical properties of nanoclusters. However, up to now, the packing model of the core and motif has typically been one-to-one. Herein, we present positional isomeric nanoclusters, Au14Cd2-1 and Au14Cd2-2, which feature an identical Au13 i...