Orthogonal Photochemistry-Confined Crystallization Enables Mechanically Robust, Printable Shape-Programmable Polymers.
Shape-programmable polymers are promising for soft robotics, minimally invasive medicine, and deployable structures. However, integrating high mechanical robustness, versatile shape programmability, and excellent printability into a single material system remains challenging. Here, an orthogonal photochemistry-confined...