Regulating Copper Nuclearity in Metal–Organic Frameworks for the Hydrogenation of Carbon Dioxide
Cu‐metalated MOFs, particularly Zr‐based frameworks, are promising CO2 hydrogenation catalysts. Tuning Cu nuclearity toward small clusters or isolated atoms is crucial for controlling product selectivity, yet very challenging. One way to achieve this is by adjusting the number of OH/H2O pairs on Zr6 nodes. While the Ui...