Reductively Passivated Ion-Conductive Interphase Enables High-Capacity Silicon Anodes for High-Energy-Density All-Solid-State Batteries.
Silicon-based all-solid-state batteries (ASSBs) promise high energy density for next-generation energy storage systems. However, the poor solid-solid contact between silicon (Si) and the solid-state electrolyte (SSE), coupled with interfacial instability during cycling, leads to lithium trapping and parasitic reactions...