Author

Christian Merten

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Open access Sep 2026

Chiroptical absorption and emission properties of chiral triarylboranes.

Due to their unique emission properties, chiral triarylboranes are of particular interest for a wide range of optical applications. Rigid chiral propeller-like superstructures can be established by incorporation of bulky substituents that slow down or even prevent the rotation along the B-C bond. In the present study,...

Sven Reese, G. Clever, Christian Merten · Physical Chemistry, Chemical... · 0 citations

Open access Sep 2026

σ- and π-hole interactions of iodotrifluoroethylene (C2F3I) with tertiary amines characterized by matrix isolation IR spectroscopy.

Under matrix isolation conditions, weakly bound complexes can be stabilized and even higher energy species can be kinetically trapped and subsequently characterized spectroscopically. Halogen bonded and π-hole complexes of iodotrifluoroethylene and different tertiary amines are identified in pH2 matrices. For ITFE-trim...

Malte Feßner, Frederike Beyer, Nora M. Kreienborg et al. · Physical Chemistry, Chemical... · 0 citations

Open access Jul 2026

Protein-confined imidazolium intermediates enable diverse biocatalytic C–C and C–N bond formations

Developing enzymatic strategies to selectively construct C–C and C–heteroatom bonds is a major objective in modern biocatalysis. Here we combine genetic code reprogramming and laboratory evolution to establish a family of allylic transferase enzymes that can achieve a remarkable breadth of chemistry, enabling the gener...

Zachary Birch-Price, A. E. Hutton, Fei Zhao et al. · Nature Catalysis · 1 citation