Heme-Proximal Loop Dynamics Modulate Mn(II) Oxidation in Pseudomonas putida MET94 DyP-type peroxidase.
Enzymatic Mn(II) oxidation is relevant to both natural lignin degradation and the development of new industrial biocatalysts. DyP-type peroxidases are versatile microbial biocatalysts with potential applications in lignocellulose valorization, but the structural features influencing their Mn(II)-oxidizing activity rema...