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Author

D. Cordes

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2 papers indexed here

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Open access Aug 2026

Controlling phosphorus(v)-stereogenicity via organocatalytic acylative desymmetrisation of bisphenols

The enantioselective construction of phosphorus(v)-stereogenic centres is of broad importance due to the utility of these compounds both as ligands in catalysis and as scaffolds in medicinal chemistry. This manuscript demonstrates the effective acylative desymmetrisation of ortho-bisphenols to access P(v)-stereogenic p...

Ffion M. Platt, Martha I. Prindl, Zhanyu Zhou et al. · 1 citation
Open access Sep 2026

Selectivity in Homolytic Substitution at a Tertiary Phosphine Center: Mechanistic Insights into Dealkanation Reaction

Here, we present a comprehensive mechanistic investigation of a transformation that reverses the usual reactivity of an established radical P–C bond-forming process. Peri-substituted compounds bearing tertiary and secondary phosphine groups undergo dealkanation to afford an alkane and a diphosphine. To examine the infl...

Bethany J. M. Lawson, Chao Tan, G. Hähner et al. · 0 citations

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