EnT-Mediated Imino-Sulfonylation of Methylenecyclopropanes Using Bifunctional N-Sulfonyl Imines: Access to β-Amino Sulfone Derivatives.
Herein, we present a visible light-driven difunctionalization strategy for the efficient synthesis of β-amino sulfone derivatives from methylenecyclopropanes and N-sulfonyl imines under mild conditions. The process involves an energy transfer (EnT)-mediated pathway, wherein homolytic N-S bond cleavage generates persist...