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Author

Fa-Kun Zheng

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Oct 2026

Additive-Induced Supramolecular and Structural Isomerism in Zn(II) MOFs: Tuning Emission from Intraligand Local Excitation to Intermolecular Charge Transfer through π-Stacking Control.

Additive-directed assembly is a powerful yet underexplored route to supramolecular isomers with tunable metal-organic framework (MOF) photophysics. Three Zn(II) MOFs, [Zn(Hbtzip)2(H2O)2]·4H2O (1), [Zn(Hbtzip)2(H2O)2] (2), and [Zn(btzip)] (3), were hydrothermally synthesized from 4,6-bis(triazol-1-yl)isophthalic acid (H...

Jian-Di Lin, Sheng-Min Hu, Hao-Hui Xie et al. · 0 citations
Sep 2026

A Twisted σ-Bond Mediated by a Lone-Pair in Elemental Sulfur

The lone pair is a foundational concept in chemistry, classically regarded as a localized, nonbonding entity. However, a persistent anomaly in elemental sulfur (S8) challenges this view: the observed electron density along the S–S bond shows a bimodal distribution that is irreconcilable with a single-peak theoretical...

Long-Qi Yang, Xiao-Ming Jiang, Fa-Kun Zheng et al. · 0 citations

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