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Sep 2026

Tuning the Frontier Molecular Orbitals of Aromatic Radicals via Chalcogen Substitution and Heterocyclic Stabilization

Due to the intrinsic electron-donating effect of chalcogen lone pairs to the aromatic rings, well-characterized radicals, including phenoxy and thiophenoxy, demonstrate that sulfur substitution for oxygen generally raises the electron affinity (EA). Here we report a counterintuitive reversal using high-resolution pho...

Ya-Ling Wang, Yun-Ye Zhang, Yi-Hao Zhou et al. · 0 citations

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