Fen-Ya Xiong

Radical Sulfinamidation of Alkenes Enabled by a PCET-HAT Relay.

Sulfinamides and related sulfur(VI) motifs are widely represented in bioactive molecules; however, their direct installation onto alkenes has traditionally relied on Lewis acid- or transition metal-mediated two-electron pathways, with more recent advances dominated by photoinduced single-electron processes. Here, we re...