Author

Gary A. Baker

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Open access Sep 2026

Molecular Engineering of Tetra(hetero)arylphosphonium Ionic Liquids: Thermally Robust, Photoluminescent Materials with Tunable Melting Thermodynamics

Ionic liquids (ILs) are deployed for high-temperature technologies, where sustained thermo-oxidative stability must be combined with additional functions in a single organic material. We report a second-generation library of 34 tetra(hetero)arylphosphonium cations paired with the [NTf2]− anion, spanning seven π-conju...

Muhammadiqboli Musozoda, Kylie M. Allen, Omar Chowdhury et al. · ACS Applied Engineering Mate... · 0 citations

Open access Aug 2026

Pyrene-Tagged Polyimidazolium Nanoclays Enable Modular Excimer Emission for Multi-Analyte Fluorescence Sensing

We introduce a modular platform for engineering excimer-active fluorescent nanoclays by covalently installing pyrene onto imidazolium-functionalized polyionic nanoclays (PINCs) using thiol-maleimide Michael addition. Precise control of pyrene surface densities (0.1–15 mol %) affords a synthetically tunable monomer–ex...

Piyuni Ishtaweera, N. E. Larm, Gary A. Baker · ACS Applied Nano Materials · 0 citations