Enantioselective Scandium-Catalyzed Benzylic C−H Addition of Tertiary Anilines to Alkenes
Enantioselective C−H addition of aromatic amines to alkenes represents a highly efficient and direct approach for the synthesis of chiral alkylanilines. Herein, we report an enantioselective benzylic C(sp3)−H addition of tertiary anilines to alkenes, enabled by a bulky anilido-oxazoline ligand-supported scandium cata...