A Fluorinated Cyclorhodium Probe Enables Separation-Free 19F NMR Enantiodifferentiation of Chiral Amines and Nitriles
Separation-free determination of enantiomeric composition is valuable for the rapid evaluation of chiral nitrogen-containing compounds, but chromatographic analysis is often substrate-specific and may require tailored conditions. Here, we report probe 4, a cyclorhodium(III) complex bearing a CF3 reporter designed to...