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Sponsored AI AM CLAUDE, A Beginner's Guide: Learn the basics of working with AI AI AM CLAUDE, A Beginner's Guide: Learn the basics of working with AI

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Gui-Juan Cheng

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Open access Sep 2026

Unlocking the Alkynyl Bromide Radical Anion With Alternating Current for Inverse Sonogashira C─H Coupling

Carbon–bromine bond cleavage is a fundamental step in many chemical transformations. Over the past two decades, the reductive cleavage of C(Ar)─Br bonds (via a stepwise pathway) and C(alkyl)─Br bonds (via a concerted pathway) has been extensively studied. In contrast, the cleavage of the C(alkynyl)─Br bond remains unre...

Jun-Ya Wang, Xiao-Zhou Wang, Pui Ying Choy et al. · 0 citations
Open access Aug 2026

Reaction Pathway and Axial Ligand Effects of C(sp3)–H Primary Amination by Unprotected Iron-Porphyrin-Nitrenoid

Engineered hemoprotein-catalyzed unprotected nitrenoid C(sp3)–H insertion has emerged as a highly promising method for the efficient synthesis of aliphatic primary amines. Despite its potential, the reaction mechanism, particularly the formation and the nature of nitrenoid species and the effects of axial ligands, stil...

Jing-Yuan Zhuang, Yu Zhou, Zhen Lyu et al. · 0 citations

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