Interfacial Phase Transformation Enabled Crystallographic Selectivity for Efficient Li2CO3 Decomposition Toward Long-Cycling Li-CO2 Batteries.
The formation and decomposition of Li2CO3 dictate the reversibility of Li-CO2 batteries. However, as an electronically insulating and stable solid, the random deposition of Li2CO3 causes interfacial blockage and high decomposition barriers, severely limiting performance. Herein, we propose a facet-preferred growth stra...