Cu(I)-based metal-organic frameworks (MOFs) are attractive for small-molecule binding and catalysis, but their practical use is often limited by oxidation state instability and framework degradation. Here, we report an all-N-coordinated Cu(I)-MOF, [Cu(imtpy)]·MeOH (2,4,5-tris(4-pyridyl)-1H-imidazole; Himtpy), containin...
Zi-Ming Ye, Hao-Miao Xie, Milad Ahmadi Khoshooei et al.· ACS Applied Materials and In...· 0 citations
Electrocatalytic hydrogenation (e -H) provides a sustainable route for converting unsaturated organic substrates under mild conditions using renewable electricity as the driving force. Here, we report an MOF-derived cobalt catalyst for the e -H of acetone and pyridine. A new two-dimensional cobalt metal-organic framewo...
B. K. Behera, Xin Zheng, Hao-Miao Xie et al.· Journal of the American Chem...· 0 citations
We report an end-to-end computational-experimental workflow for the discovery of metal-organic frameworks (MOFs), demonstrated by the computational design and synthesis of two novel Zn-based frameworks, UCHI-1 and UCHI-2, exhibiting enhanced methane uptake and selectivity at low pressure under ambient conditions (298 K...
A. Darù, Jianheng Ling, Xiaoliang Wang et al.· Journal of the American Chem...· 1 citation
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