Unlocking Efficient Sacrificial-Agent-Free Photocatalytic Nitrogen Fixation via a Polyoxometalate/Cyanoviologen Type-II Heterojunction with Synergistic Electron Transfer
For the photocatalytic reduction of dinitrogen in aqueous media, rational design of the catalyst-reactant interface is critical for achieving efficient charge dynamics and molecular activation. Herein, we constructed a type-II heterojunction based on silicomolybdic acid (SiMo12) and cyanoviologen-based coordination p...