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Author

Janakiram Vaitla

2 papers indexed here

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Sep 2026

Reductive activation of vinyl sulfoxonium ylides enables divergent radical-mediated carbon-carbon bond formation.

Vinyl sulfoxonium ylides are traditionally confined to two-electron cyclization chemistry, limiting their utility in intermolecular C-C bond formation. Herein, we demonstrate that reductive activation of vinyl sulfoxonium ylides under Zn/TiCl4 conditions unlocks a distinct radical reactivity manifold. Depending on the...

Raghunath Polai, D. K. Gopalakrishnan, Janakiram Vaitla · 0 citations
Sep 2026

A Reagent-Controlled Divergent Route to Pyranone Scaffolds via Formal Insertion of Vinyl Sulfoxonium Ylides into Activated Alkenes.

A reagent-controlled divergent reaction of vinyl sulfoxonium ylides with arylideneindane-1,3-diones has been developed. The transformation proceeds through in situ formation and selective cleavage of donor-acceptor cyclopropane intermediates, providing dihydropyranone and indenopyranone scaffolds with excellent regio-...

Shalu Deshwal, Janakiram Vaitla · 0 citations

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