Polyol-Mediated Suppression of Paddlewheel Hydrolysis Enables Biomimetic Mineralization of Unstable Metal-Organic Frameworks.
Hydrolytically unstable metal-organic frameworks (MOFs) remain difficult to synthesize under aqueous, biocompatible conditions, limiting their integration with biomacromolecules. Here, we report a polyol-assisted aqueous strategy for the synthesis of highly crystalline HKUST-1 with tunable particle size under mild cond...