Copper(I)-Catalyzed Asymmetric Hydrogermylation of 3,3-Disubstituted Cyclopropenes.
Catalytic asymmetric approaches to enantioenriched organogermanium compounds remain severely underdeveloped. Herein, we report a CuOAc-catalyzed enantioselective hydrogermylation of 3,3-disubstituted cyclopropenes, which furnishes structurally diverse chiral organogermanes in high to excellent diastereo- and enantiosel...