The Exact Maximum of the Spectral Sum of Graphs
For a simple graph $G$ of order $n$, let $S_2(G)=\lambda_1(G)+\lambda_2(G)$ denote its spectral sum. We determine, for every $n\geq5$, the exact maximum of $S_2(G)$ and all equality cases. The unique maximizer, up to isomorphism, is the complement of the disjoint union of a suitably balanced complete bipartite graph and isolated vertices, with the sizes of its three parts determined by $n$ modulo $7$. Denoting this graph by $K_n^\star$, we further show that $ S_2(K_n^\star)\leq\frac{8n}{7}-2,$ with equality exactly when $7\mid n$. This proves a conjecture of Kumar, Liu, Monterde, Pragada and Tait, which strengthens the Aouchiche--Hansen 2010 conjecture by extending it from connected graphs to all graphs and by asserting uniqueness of the extremal graph. The result also subsumes the 2008 conjecture of Ebrahimi B., Mohar, Nikiforov, and Ahmady. The proof combines Ky Fan's variational principle with a spectral inequality for weighted Ferrers quotients to reduce the problem to an explicit family whose complements have incidence rank one. Exact integer optimization and a separate equality analysis then yield the maximum and uniqueness.