Windmill-Type π-Extension Within Donor Moiety of Covalent Organic Framework Boosts Overall Photocatalytic Hydrogen Peroxide Production.
Covalent organic framework (COF)-based catalysts are promising for overall photocatalytic hydrogen peroxide (H2O2) production, yet the sluggish kinetics of water oxidation reaction (WOR) and inefficient charge carrier processes limit the catalytic performance. Herein, by modulating the donor structure of COF where the...