Designing a Hexanickel Cluster-Functionalized Polyoxometalate Hybrid for Photothermally Driven P(O)-S Bond Formation.
The widespread applications of sulfur-containing organophosphorus compounds across organic synthesis, medicinal chemistry, and agricultural chemistry necessitate efficient methodologies for the formation of P(O)-S bonds. Herein, we developed a protocol for the cross-dehydrogenative coupling (CDC) of thiols and P(O)H co...