Cobalt-Catalyzed Enantioselective Intermolecular C–H Carboamination with Racemic Allenes
Enantioselective carboamination of allenes especially in conjunction with 3D-metal catalysis remains a significant challenge. We report chiral cyclopentadienyl cobaltIII-catalyzed regio-, chemo-, and enantioselective intermolecular C–H carboamination of racemic allenyl esters with N-phenoxyisobutyramides. The protoco...