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Author

Li-Ping Zhang

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Oct 2026

Discovery and semisynthesis of coniochaetones N-P: antimicrobial and antioxidant heterocyclics from an Antarctic-derived fungus Penicillium sp. S2014503.

Penicillium sp. S2014503 is a fungus found in the Antarctic. Herein, we report a new heterocyclic (1) and two semi-synthesized ones (2-3) derived from citrinin (4), the main product of S2014503. Absolute configurations of 1 and 4 were deduced by single crystal X-ray diffraction analyses. Compound 2 was analyzed to be a...

Hai-Bo Zhang, Imran Khan, Wen-Yu Cheng et al. · 0 citations
Aug 2026

A Cytochrome P450 Enzyme-Catalyzed Acetyl Migration in Cyanogramide Biosynthesis.

It is demonstrated that the cytochrome P450 monooxygenase CyaI catalyzes an oxidation reaction through a zwitterionic intermediate and facilitates a subsequent unusual C→N acetyl migration, which triggers a spontaneous intramolecular cyclization to forge the imidazolidin-4-one ring during 1 biosynthesis.

Yiguang Zhu, Yongchao Wang, Li-Ping Zhang et al. · 0 citations

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