Gram-Scale Synthesis of N2-Type Ag32 Superatomic Molecule and Its Catalytic Reduction of 4-Nitrophenol.
Cluster assembly serves as an effective approach for tuning cluster properties, where the electronic states arising from fused units play a crucial role in property design, thus attracting attention. In this work, we synthesized a Ag32 cluster via a one-pot method, featuring a Ag22 core formed by fusion of two icosahe...