Luca Massaro

Cross-Couplings via Electroreductive C–F, C–O, and C–S Bond Cleavage and Radical-Polar Crossover Mechanisms

Electrochemical synthesis has emerged as a powerful platform for generating reactive intermediates under conditions that are difficult to achieve with conventional chemical reductants or oxidants. In particular, cathodic electron transfer to polarized C–X bonds can provide direct access to carbon-centered radicals, w...