M. Icker

Macrocyclic zinc complexes for stabilisation of non-linear NH⋯S bonds in solution and solid state.

The structural and spectroscopic properties of well-defined NH⋯S hydrogen bonding interactions is scarce in the literature, only few suitable model compounds have been described. Herein, we describe a set of macrocyclic Zn amino-thiophenolato complexes and their deuterated derivatives, in which secondary amino groups a...