3 d Transition Metal Contribution to the Magnetic Behavior of Chiral Y6 M x Si2S14 and Tb6CoSi2S14
A series of quaternary rare-earth sulfide materials Y6MxSi2S14 (M = Ti, V, Cr, Mn, Co, Ni) and Tb6CoSi2S14 were synthesized by solid-state methods to investigate the effects of the 3d transition metal on the respective magnetic properties. The elemental composition was confirmed by single-crystal X-ray diffraction (S...