Freezing-Induced Modulation of Molecular Motion and Self-Assembly in the Water/Dimethyl Sulfoxide/Polyoxyethylene (20) Oleyl Ether Micellar Solution System.
Freezing of multicomponent aqueous systems generates pronounced compositional gradients and interfacial heterogeneity that strongly influence molecular dynamics and self-assembly. Here, we investigate the effects of ice formation on molecular motion and micellar organization in a water/dimethyl sulfoxide (DMSO)/polyoxy...