Engineering the Electrochemical Interface With Polyborate for High-Selectivity Adiponitrile Electrosynthesis.
The electrochemical dimerization of acrylonitrile (AN) to adiponitrile (ADN) offers a sustainable pathway for producing Nylon-66 precursors. However, its efficiency is severely limited by competitive hydrogen evolution, often demanding toxic heavy metals and non-electrochemical hydrolysis induced by local pH changes. H...