Side-Chain-Induced Interlayer Slipping in Metalloporphyrin COFs Enables Microenvironment and Spin-State Regulation for Photocatalytic CO2 Reduction.
Photocatalytic CO2 reduction (CO2RR) involves a cascade of intrinsically coupled processes, rendering the independent optimization of catalytic kinetics and thermodynamics challenging. In this study, we introduce a structural regulation strategy via steric-driven interlayer slipping engineering of metalloporphyrin-base...