Ligand-Controlled Stereodivergent Cobalt-Catalyzed Hydroboration of 2,3-Disubstituted 1,3-Dienes to Access E- and Z-Tetrasubstituted Alkenes.
Stereodivergent synthesis to access multiple isomers of polysubstituted alkenes represents an elegant strategy. While significant progress has been made in accessing di- and trisubstituted alkenes, the stereodivergent synthesis of both Z and E isomers of tetrasubstituted alkenes remains limited. Here, we disclose cobal...