Restoring Adhesion–Cohesion Balance in High Bio-Content Waterborne Pressure-Sensitive Adhesives through Itaconate Chemistry and Nanocellulose Reinforcement
High biobased content waterborne pressure-sensitive adhesives (PSAs) were developed via seeded semi-continuous emulsion polymerization using renewable monomers including dibutyl itaconate (DBI), 2-octyl acrylate (2-OA), isobornyl acrylate (IBOA), and isobornyl methacrylate (IBOMA), achieving biobased contents up to 7...