Electronic spectroscopy and photochemistry of cis and trans-HNNO.
Diazene oxide (HNNO) is a chemically strategic transient that links N2O to more reactive nitrogen reservoirs and can control branching in H + N2O networks under pressure- and radiation-dependent conditions. The electronic structure, spectroscopy, and photodissociation mechanisms of the cis and trans isomers of the HNNO...