Node Distortions as a Means of Defect Engineering in Zr-Based MOFs
Defect engineering in Zr-based metal–organic frameworks (Zr-MOFs) has focused primarily on missing-linker defects. However, recent studies suggest that node dehydroxylation–which creates distortions and coordinatively unsaturated Zr sites (Zrcus)–may have a more significant impact on properties. The present work uses p...