Author

Paul H. Oyala

3 papers indexed here

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Oct 2026

Iron Intermediates in Aminoquinoline-Directed C(sp2)-H Activation/C-C Coupling.

Over the past two decades, iron-catalyzed aminoquinoline-directed C-H functionalization has attracted significant attention due to the low cost and sustainability of iron, the mild conditions required for catalysis, and the novel mechanistic manifolds compared to those with other first row metals. This report describes...

E. L. Nolan, Zi-Yan Wang, Feng-Rui Qu et al. · Journal of the American Chem... · 0 citations

Sep 2026

Co(0)-Arene Complexes Derived from a Co4 Cluster: Synthesis, Characterization, and Hydrogenation Catalysis

Low-valent cobalt complexes have emerged as effective earth-abundant pre-catalysts for olefin hydrogenation reactions. Here, we report a series of heteroleptic Co(0) arene cyclic (alkyl)(amino)carbene (CAAC) complexes that catalytically hydrogenate olefins. Whereas direct reduction of CAACCo(II) precursors affords pr...

Graden Snyder, Joshua Thedford, C. Andre et al. · Inorganic Chemistry · 0 citations

Sep 2026

Experimentally Validated Cobalt Phosphinothiolate Hydride Intermediate Governs the Selectivity Switch between Formate and Syngas in CO2 Reduction

Controlling product selectivity in homogeneous electrocatalytic CO2 reduction remains a significant challenge, often requiring complicated catalyst redesigning. Herein, we identify and validate a cobalt-hydride intermediate that governs the selectivity switch for CO2 reduction to either formate or synthesis gas (syng...

David A. Velazquez, Adya A. Mahapatra, Sevak T. Pogosyan et al. · ACS Catalysis · 0 citations