Atomically Asymmetric Pd1─O─Cu Interfaces Break the Activity-Selectivity Limit in CO-to-Acetate Conversion.
The electrochemical reduction reaction of CO (eCORR) to acetate is a pivotal pathway for carbon neutrality, yet it is persistently constrained by the linear scaling relations of the adsorption energetics of key intermediates. Consequently, conventional alloy catalysts often suffer from an activity-selectivity trade-off...