Giant Internal Electric Field in Ni-Modified Perylenetetracarboxylic Acid Supramolecule via Metal-Coordination Engineering for Efficient Photocatalytic H2 Evolution.
Developing efficient supramolecular photocatalysts is essential for green H2 production using solar energy, yet their performance is often limited by inefficient photogenerated charge separation. Herein, this study innovatively employs the coordination-driven self-assembly of Ni2+ ions and perylenetetracarboxylic acid...