Peng-Yuan Zhang

Iron-Electrocatalytic MHAT Enables C–F Bond Activation of CF3 Alkenes: Access to Stable Keto and Enol Isosteres

Iron-catalyzed metal hydride hydrogen atom transfer (MHAT) is a powerful strategy for hydrofunctionalization of alkenes, where reactive Fe–H is generated from a hydride donor through an oxidative process. Here, we report an iron-electrocatalytic MHAT reaction based on reductive generation of Fe–H directly from proton...