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Philip Troycke

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Open access Aug 2026

Local Active-Site Architecture Directs Divergent Carbocation Cascades in Sesterterpene Synthases.

Type I terpene synthases generate complex polycyclic scaffolds through carbocation cascades. However, how closely related enzymes convert a common C25 precursor to distinct sesterterpene frameworks remains unresolved. Here, we combine high-resolution crystal structures with systematic mutagenesis of four bacterial sest...

Philip Troycke, Heng Li, Ke-Xin Yang et al. · 0 citations

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