Anion-Doped Manganese Oxides Enabling Relay Catalysis for Aerobic Alcohol Ammoxidation.
The development of noble-metal-free heterogeneous catalysts for room-temperature aerobic ammoxidation of alcohols to nitriles represents an enduring challenge, primarily hampered by unselective lattice-oxygen over-oxidation via the classical Mars-van Krevelen (MvK) pathway and strong site-blocking effects. Herein, we r...