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Quan-Li Shen

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Open access Aug 2026

Thermodynamic Locking of Conformational Chirality in a [9]Cycloparaphenylene

Herein, we report the thermodynamic locking of conformational chirality in a [9]cycloparaphenylene (CPP) by external appending of (R)- or (S)-BINOL units. Through-space steric interactions induce asymmetric torsion in the CPP backbone, generating a strained nanohoop with the lowest-energy conformer (ΔG = −2.9 kcal mol–...

Zhi Zhang, Quan-Li Shen, Ze-Kang Ma et al. · 0 citations

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