Reactivity of Cobalt(III) vs Rhodium(III): Role of Multispin Energy Surfaces in the Regio- and Enantioselective Intermolecular Carboamination
Asymmetric nonannulative intermolecular carboamination via C–H activation represents a powerful strategy for converting inexpensive alkene feedstocks into value-added products. A comprehensive study was conducted on the reaction mechanism and origin of selectivity with acrylate and N-phenoxyacetamide as substrates, w...